Making and Testing Esters – The Smell of Chemistry
Few experiments appeal to the senses quite like ester formation. When acids and alcohols react, they produce pleasant, fruity-smelling compounds called esters. From artificial flavours to perfumes and solvents, esters show how organic chemistry connects directly to everyday life.
The Experiment
Students mix a carboxylic acid with an alcohol in the presence of an acid catalyst — usually concentrated sulfuric acid.
A simple school-level method involves:
-
Placing 1 cm³ of alcohol and 1 cm³ of carboxylic acid into a test tube.
-
Adding a few drops of concentrated sulfuric acid.
-
Gently warming the mixture in a water bath for a few minutes.
-
Pouring it into a beaker of water to smell the resulting ester (wafting carefully, not directly).
Common examples include:
| Alcohol | Carboxylic Acid | Ester Formed | Characteristic Smell |
|---|---|---|---|
| Ethanol | Ethanoic acid | Ethyl ethanoate | Pear or nail polish remover |
| Methanol | Butanoic acid | Methyl butanoate | Pineapple |
| Pentanol | Ethanoic acid | Pentyl ethanoate | Banana |
The Science
The reaction is a condensation reaction, where two molecules combine and eliminate water:
Sulfuric acid acts as a catalyst and dehydrating agent, helping the equilibrium shift toward ester formation.
Students learn about reversible reactions, equilibrium position, and how structure determines smell.
Skills Highlight
-
Safely handling and heating volatile organic liquids
-
Observing and describing qualitative results (odour, appearance)
-
Understanding esterification as a reversible condensation reaction
-
Linking molecular structure to real-world products in industry and biology
Why It Works in Teaching
Making esters connects chemical theory with sensory experience. Students smell the result of their reaction and see chemistry as something tangible, memorable, and creative — a perfect example of applied organic chemistry.










