What Is Hiding in White Light?
Diffraction and Spectroscopy in the Home Laboratory
Two lamps can both look white, yet produce remarkably different spectra. A spectroscope reveals the difference—and a diffraction grating can turn those colours into measurements.
Switch on a table lamp, an LED torch and a fluorescent light. To our eyes, each may provide something we comfortably call “white light”.
But does that mean they contain the same mixture of wavelengths?
Look through a spectroscope and an ordinary light source becomes something worth investigating. You might see a smooth spread of colours, bright narrow lines, or broad bands with brighter and dimmer regions.
For me, spectroscopy is a particularly satisfying meeting point between chemistry and physics. As a spectroscopy lecturer, I value the connection between a visible pattern and the process producing it. The interesting question becomes:
“What does this spectrum tell us about the source?”
This investigation can begin with children describing colours and develop into A-level work on diffraction, wavelength and electron energy levels.
Time: 45–60 minutes for comparing sources; allow another 30–45 minutes for quantitative measurements.
The challenge: Can you identify a light source from its spectrum—and measure the wavelength of one of its bright lines?
Start with a Prediction: Is All White Light the Same?
Before showing anyone a spectrum, ask them to predict what they will see.
- Will every white lamp produce a complete rainbow?
- Will a red LED produce one perfectly sharp red line?
- Will daylight resemble an incandescent lamp?
- Could two lamps look similar while producing different spectra?
Write down the predictions before switching on the equipment.
My teaching preference is to begin with something familiar, let the evidence raise a question, and introduce the theory when it has a job to do. Here, the familiar object is simply a lamp.
What You Need
For the first investigation:
- A handheld spectroscope, or an enclosed slit-and-diffraction-grating viewer.
- Several light sources: an incandescent lamp if available, white and coloured LEDs, and an intact fluorescent lamp.
- Diffuse daylight or daylight reflected from matt white paper.
- A notebook and coloured pencils.
- Optionally, a camera or phone to record the spectra.
For quantitative measurements, add a transmission grating with a known line density and a suitable optical spectrometer with an angular scale.
A handheld spectroscope is excellent for comparisons. It needs a calibrated scale or an appropriate measuring arrangement before it can provide reliable wavelengths.
Set Up Safely
Never look directly at the Sun through a spectroscope, diffraction grating or other optical instrument. Use diffuse or reflected daylight, keeping the instrument away from the Sun’s direction.
Use ordinary low-intensity lamps. Keep hot incandescent bulbs clear of paper and fingers, and leave mains fittings intact.
Educational discharge tubes should be used only with their correct holder and matching power supply, under competent adult control. They can involve high voltage and hot glass. Follow the manufacturer’s instructions before changing tubes.
Keep fluorescent lamps intact. Lasers, high-power LEDs and UV lamps are unnecessary for this investigation.
Why a Diffraction Grating Separates Colours
A transmission diffraction grating contains many closely spaced, regularly arranged lines or openings.
Light diffracts at the openings. The emerging waves overlap and interfere. At particular angles, they reinforce one another, producing bright images of the entrance slit.
Different wavelengths reinforce at different angles, separating the light into a spectrum.
For a given non-zero order, red appears farther from the straight-through direction than violet. The central, zero-order image contains the wavelengths together.
A prism also separates colours, but through wavelength-dependent refraction. A grating uses diffraction and interference.
That difference matters: the spectrum becomes visible evidence of wave behaviour.
The First Investigation: Compare Your Light Sources
Dim unnecessary room lighting, while keeping enough light to work safely. Observe one source at a time and keep other lamps out of the field of view.
Begin with a moderately narrow entrance slit. Narrowing it generally sharpens features, but also makes the spectrum dimmer.
Keep the same colour orientation in every sketch.
| Source | What you may observe | What it suggests |
|---|---|---|
| Incandescent lamp | A continuous spread of visible colours | Thermal radiation from a hot filament |
| White LED | Often a conspicuous blue region and broader emission at longer wavelengths | A mixture shaped by the LED and its phosphor |
| Coloured LED | A relatively narrow band | Emission over a limited wavelength range |
| Fluorescent lamp | Bright narrow features over broader emission | Gas emission combined with phosphor emission |
| Diffuse daylight | A broadly continuous spectrum; fine dark lines require sufficient resolution | Sunlight modified by absorption |
These are expectations to investigate, rather than pictures students should copy.
NASA’s classroom activity describes the continuous spectrum of an incandescent filament and the combination of mercury lines and phosphor emission in fluorescent lighting. stereo-ssc.nascom.nasa.gov
Incandescent Light: Continuous Does Not Mean Uniform
An incandescent lamp produces light because its filament is hot.
The visible colours blend into one another rather than appearing as isolated narrow lines. However, a continuous spectrum does not contain equal amounts of every wavelength.
Ask:
“Can we distinguish the colours present from their relative brightness?”
That question helps students move beyond treating every continuous spectrum as an identical rainbow.
LEDs: More Interesting Than “One Colour”
A coloured LED emits a band of wavelengths rather than one infinitely precise wavelength.
Many white LEDs combine a blue-emitting semiconductor with phosphor material that produces broader emission at longer wavelengths. Other designs exist, so students should compare real lamps rather than assume every LED behaves identically. gigahertz-optik.com
Try comparing warm-white and cool-white lamps. Can you distinguish their balance of colours?
This connects naturally with photography and video. It provides a starting point for investigating why fabrics, painted objects and skin can look different under different lamps. A visual spectrum alone, however, is not a complete measurement of colour-rendering quality.
Fluorescent Lamps: Look for More Than Lines
A fluorescent lamp resists an oversimplified explanation.
Look for sharp features and the broader background separately. Ask students to describe both before discussing how the lamp works.
A useful observation might be:
“Several narrow features are much brighter than the surrounding colours, but there is also broader emission between them.”
That is a stronger scientific description than simply writing “a line spectrum”.
Daylight: More Detail Than the Eye First Reveals
A simple viewer may show daylight as a continuous rainbow. Higher-resolution observations reveal dark absorption lines in the solar spectrum.
These features help scientists investigate the material through which the light has passed. NASA Science
Do not promise that every inexpensive spectroscope will reveal them.
Failure to resolve a feature does not establish that it is absent.
That is an important lesson about instruments as well as light.
Record Evidence, Not Just Pretty Colours
For each source, record:
- Its identity and apparent colour without the spectroscope.
- Whether the spectrum looks continuous, banded, lined or mixed.
- The positions of conspicuously bright or dark features.
- A labelled sketch.
- One possible explanation and one remaining question.
For example:
“White LED: blue region particularly bright, with broader emission towards green, yellow and red. Possible explanation: blue LED plus phosphor. Question: would another white LED show the same pattern?”
Avoid adding an invented wavelength scale. Until calibrated, the sketch records colour and position.
Photographs are useful, but camera sensors, exposure and processing affect their appearance. Keep settings consistent where possible and avoid overexposing bright features. Treat the images as records rather than calibrated intensity measurements.
From Seeing Colours to Measuring Wavelength
With suitable measuring equipment, the grating equation makes the investigation quantitative.
For light incident perpendicular to the grating:
d * sin(theta) = n * wavelength
Where:
- d is the spacing between adjacent grating lines, in metres.
- theta is the angle from the straight-through direction to the selected line.
- n is the diffraction order; use n = 1 for the first-order spectrum.
- wavelength is measured in metres.
A grating’s quoted line density is not its line spacing. For 600 lines per millimetre:
d = 0.001 / 600 m
d = approximately 1.67 * 10^-6 m
The equation applies to the correctly aligned optical arrangement, rather than any arbitrary viewing angle. physics.columbia.edu
Worked Example: A Green Line Becomes a Number
Suppose a green line appears at 19.1 degrees in the first-order spectrum.
These are illustrative measurements, rather than results from an experiment already performed.
wavelength = d * sin(theta) / n
wavelength = (0.001 / 600) * sin(19.1 degrees) / 1
wavelength = approximately 5.45 * 10^-7 m
Since 1 nm = 10^-9 m:
wavelength = approximately 545 nm
This is close to the prominent mercury green line at about 546.1 nm in NIST’s reference data. physics.nist.gov
A visible colour has become a measurable physical quantity.
One matching line provides supporting evidence. Comparing several lines gives a stronger basis for identifying a source.
Make the Geometry Earn the Answer
Follow the spectrometer’s instructions to focus and align the instrument. Establish the straight-through direction, then measure the chosen first-order line on both sides.
For a correctly aligned, symmetric arrangement, half the angular separation between those positions gives theta. Repeat the readings.
Check that students have measured the diffraction angle, selected the correct order and converted the grating spacing into metres.
How Close Is Close Enough?
Suppose the result is 545 nm and the reference value is 546.1 nm.
Percentage difference from reference = absolute(measured value - reference value) / reference value * 100
Percentage difference = absolute(545 - 546.1) / 546.1 * 100
Percentage difference = approximately 0.20%
This does not mean the measurement uncertainty is 0.20%.
Agreement with a reference and uncertainty are different ideas.
Discuss the precision of the angular scale, variation between repeated readings, slit width and alignment.
A calculator displaying many digits cannot make an uncertain angle precise.
That makes this practical valuable preparation for evaluating experimental results.
Why Atoms Produce Characteristic Lines
In an isolated atom, electrons occupy particular allowed energy levels.
When an excited atom makes a transition to a lower energy state, it can emit a photon. The photon’s energy corresponds to the difference between those levels.
In standard text:
energy difference = h * c / wavelength
Here h is Planck’s constant and c is the speed of light in a vacuum; the expression uses the photon’s vacuum wavelength.
Different elements have different energy-level arrangements, giving characteristic patterns of lines. Those patterns can help identify the elements present. Introduction
This is where chemistry and physics meet: diffraction helps us measure the wavelengths, while atomic structure helps explain them.
The simple isolated-atom explanation should not be applied unchanged to a hot filament or a semiconductor LED.
Three Ways to Take the Investigation Further
1. Identify a Mystery Source
Let an adult select a previously studied lamp, concealing its identity while preserving ventilation and safe access.
Can students identify it from its spectrum?
Require two observed features to support the answer. The task becomes evidence-based classification.
2. Compare Two White LEDs
Compare warm-white and cool-white lamps, or two different models.
Sketch their spectra, then examine coloured objects under each source.
Does “white” describe a single mixture of wavelengths?
Avoid inferring electrical efficiency or health effects from this visual comparison.
3. Connect the Bench to the Stars
Astronomers compare spectral features with laboratory measurements to investigate distant objects. Spectra also carry information about temperature and motion. ESO
Students can explore that connection using published solar spectra and reference emission lines.
Light carries evidence about matter we cannot visit or sample. The laboratory comparison gives that extraordinary idea a practical starting point.
Why I Value This Kind of Practical Teaching
At Hemel Private Tuition, I want practical work to support the reasoning students need in GCSE and A-level science.
This investigation offers a natural progression:
Observe a difference. Describe it accurately. Suggest an explanation. Measure it. Check the evidence. Consider the limitations.
A younger student can compare colours. An older student can calculate a wavelength, discuss uncertainty and explain electron energy transitions.
The practical remains recognisably the same while the thinking becomes more demanding.
For students who find wave equations or atomic structure abstract, the visible starting point can be particularly helpful. The calculation answers a question about something they have actually seen.
Conclusion: An Ordinary Lamp Becomes a Scientific Question
A lamp can illuminate a room while concealing the details of how it produces its light.
A spectroscope reveals those details. A diffraction grating, used with a suitable measuring arrangement, lets us investigate them quantitatively.
What begins with household lamps can lead to interference, atomic structure, uncertainty and the chemistry of stars.
Choose three light sources, predict their spectra, and compare them. Which source surprises you most?
If you would like to explore GCSE or A-level science through practical work linked to explanation and exam technique, contact Hemel Private Tuition.



