Why Water Has a Skin: Surface Tension, Plants and Walking on Water
A pond skater appears to perform the impossible.
Its body is denser than air, its legs press down on the surface of a pond, and yet it does not sink. Instead, it races across the water as though the surface were covered by a thin, transparent sheet.
Elsewhere, water is performing another apparently impossible trick. Inside a plant, it travels upwards from the roots towards leaves that may be many metres above the ground. In a narrow glass tube, water can rise above the level of the surrounding liquid, apparently moving against gravity.
There is no actual skin covering the water, and the water is not defying gravity. These effects are produced by the forces acting between molecules.
Surface tension and capillary action are sometimes mentioned only briefly in school science. However, they are involved in plant transport, breathing, cleaning, printing, waterproof clothing, medical technology and the lives of organisms that inhabit the surface of ponds.
They provide a wonderful example of how invisible forces at the molecular level can create effects large enough for us to see.
The Central Question
How can insects walk on water, and how can water climb upwards against gravity?
To answer this, we first need to consider what is happening between individual water molecules.
Why Water Molecules Attract One Another
A water molecule contains one oxygen atom bonded to two hydrogen atoms.
The electrons in these bonds are not shared completely evenly. Oxygen attracts the electrons more strongly than hydrogen, producing a molecule with a slightly negative region around the oxygen atom and slightly positive regions around the hydrogen atoms.
Water is therefore a polar molecule.
The slightly positive hydrogen region of one water molecule is attracted to the slightly negative oxygen region of another. These attractions are called hydrogen bonds.
A hydrogen bond is not as strong as the covalent bonds holding the atoms within a water molecule together. However, enormous numbers of hydrogen bonds acting together give water several unusual and important properties.
One of these is surface tension.
What Is Surface Tension?
A water molecule well below the surface is surrounded by other water molecules. It is attracted in many different directions, so the forces acting on it are approximately balanced.
A molecule at the surface is in a different situation.
There are water molecules beside it and below it, but comparatively few water molecules above it. The forces are therefore unbalanced, producing a net pull towards the liquid.
This causes the surface to contract towards the smallest possible area. It behaves rather like a flexible film stretched across the top of the water.
This effect is called surface tension.
The water has not formed a separate solid layer. The “skin” is simply the result of cohesive forces between molecules at the surface.
Why Water Forms Rounded Drops
Surface tension explains why small drops of water tend to be approximately spherical.
For a given volume, a sphere has the smallest possible surface area. By pulling the surface inwards, surface tension encourages the drop to adopt a shape that minimises its exposed surface.
Gravity distorts larger drops, particularly when they are resting on a surface. Nevertheless, the rounded shape can still be seen in water droplets on a waxed car, a waterproof coat or the leaf of a plant.
The shape also depends on whether water is more strongly attracted to itself or to the material beneath it.
On clean glass, water tends to spread because the attraction between the water and the glass is relatively strong.
On wax or a water-repellent surface, the attraction between water molecules is stronger than the attraction between the water and the surface. The water therefore beads into rounded droplets.
Can a Steel Needle Really Float?
A steel needle is much denser than water. If it is pushed beneath the surface, it will sink.
However, it is possible to place a dry needle or paperclip carefully on the surface so that it remains there.
The paperclip is not floating in the ordinary sense through buoyancy alone. Its weight causes the surface to bend slightly, but surface tension around the object provides an upward component of force.
The demonstration works best when the object is lowered gently using a small piece of tissue paper or a bent paperclip.
Once the tissue becomes wet, it sinks away while the needle or paperclip remains supported by the water’s surface.
This experiment is particularly effective because students already “know” that metal sinks. The surprise creates an immediate reason to investigate what is happening.
A useful classroom question
Ask students to predict what will happen if one drop of washing-up liquid is added some distance away from the floating paperclip.
The paperclip usually sinks almost immediately.
The detergent has reduced the surface tension. The invisible surface that was helping to support the paperclip is no longer strong enough to do so.
The Pepper and Detergent Demonstration
Another simple demonstration uses a shallow dish of water, ground pepper and a small amount of detergent.
Sprinkle the pepper across the surface of the water. Touch the centre of the water with a cotton bud dipped in washing-up liquid.
The pepper rapidly moves towards the outside of the dish.
It can look as though the detergent is “repelling” the pepper, but the explanation is more interesting.
The detergent reduces surface tension where it touches the water. The surface tension remains greater elsewhere, so the surrounding surface pulls away from the lower-tension region, carrying the floating pepper with it.
This movement caused by differences in surface tension is related to the Marangoni effect.
The experiment is dramatic, inexpensive and easy to repeat. However, it should not be described simply as “the soap pushing the pepper away”. It is the difference in surface tension across the water that produces the movement.
How Many Drops Can Fit on a Coin?
One of the simplest investigations involves placing water droplets onto a coin.
A student might predict that only a few drops will remain before the water spills over the edge. In practice, a surprisingly large number can often be added.
As more water is added, a curved dome forms above the coin.
Surface tension holds the droplets together and allows the water to extend above the edge for a time. Eventually, the weight of the growing drop becomes too great, the surface breaks and the water spills.
This can be turned into a useful investigation.
Students can compare:
plain water;
water containing detergent;
warm and cold water;
different coins;
clean and greasy coin surfaces;
different dropper heights;
different concentrations of detergent.
The experiment also teaches an important lesson about controlling variables.
Two groups may obtain very different results because their droppers produce different-sized drops. Counting drops is only a fair comparison when the size of each drop is reasonably consistent.
A more advanced investigation could measure the mass of water held on the coin rather than simply counting the drops.
How Can Insects Walk on Water?
Pond skaters and other water-walking insects make use of surface tension, but their success depends on more than simply being light.
Their legs are covered with microscopic water-repellent hairs. These hairs prevent the legs from becoming wet and spread the insect’s weight over a larger area.
When a water strider stands on the surface, each leg produces a visible depression in the water. The surface curves downwards but does not break.
Surface tension acting around these depressions provides an upward force that helps support the insect.
The insect can also move by pushing backwards against the surface. The surface transmits this force, allowing the animal to accelerate forwards without breaking through the water.
This is a highly specialised biological adaptation. A water strider with contaminated or damaged leg hairs may lose some of its ability to remain on the surface.
Pollution that changes the surface tension of water can also affect organisms adapted to life at the air–water boundary.
What Is Capillary Action?
Capillary action is the movement of a liquid through a narrow space, sometimes against the pull of gravity.
It depends on several interacting forces.
Cohesion is the attraction between molecules of the same substance. In water, cohesion is produced largely by hydrogen bonding between water molecules.
Adhesion is the attraction between different substances. Water molecules, for example, can be attracted to the surface of glass.
When a narrow glass tube is placed in water, water is attracted to the glass and moves slightly up the sides of the tube. Cohesion then pulls neighbouring water molecules upwards.
The narrower the tube, the more important the surface forces become compared with the weight of the liquid column. Water therefore rises higher in a narrow capillary tube than in a wider one.
The water does not continue rising indefinitely. It reaches a height at which the upward effects of adhesion and surface tension are balanced by the weight of the water column.
The Curved Surface Inside a Tube
When water rises in a glass capillary tube, its surface forms a curved shape called a meniscus.
For water in clean glass, the edges rise higher than the centre, producing a concave meniscus. This happens because the attraction between the water and the glass is strong.
Not every liquid behaves in the same way.
The shape and direction of capillary movement depend on the balance between cohesion within the liquid and adhesion between the liquid and the tube.
This is why comparing different liquids can be more informative than investigating water alone.
In a school laboratory, safe comparisons might include water, coloured water, vegetable oil and suitable alcohol–water mixtures under appropriate supervision.
Demonstrating Capillary Action with Tubes
Place several clean glass capillary tubes of different internal diameters into coloured water.
Students should observe that the water rises to different heights.
The narrowest tube should produce the greatest rise.
This can be investigated quantitatively by measuring:
the internal diameter of each tube;
the height reached by the liquid;
the type of liquid;
the temperature;
the cleanliness of the glass.
Cleanliness is particularly important. Grease on the inside of the tube changes the interaction between the water and the glass and may produce inconsistent results.
This is a useful reminder that unexpected experimental results are not always caused by an incorrect theory. Sometimes the apparatus has introduced an uncontrolled variable.
Coloured Water Between Glass Plates
Capillary action can also be demonstrated using two clean glass plates.
Place the plates close together with a very small gap between them, then allow their lower edges to touch coloured water.
The water moves upwards into the narrow space.
If the plates are closer together at one end than at the other, the water will rise further where the gap is narrowest.
This produces a visible pattern that shows how strongly capillary rise depends on the size of the space through which the liquid is moving.
Paper towels provide an even simpler example. Their fibres create many tiny spaces that act as capillary channels. Water moves between the fibres, allowing a towel to draw up a spill.
Does Capillary Action Pull Water to the Tops of Trees?
This is an area where school explanations can become misleading.
Capillary action contributes to the movement of water through narrow spaces, and the walls of xylem vessels attract water molecules. However, capillary action alone cannot account for water rising to the tops of tall trees.
The main mechanism is usually explained by the cohesion–tension theory.
Water evaporates from the moist surfaces inside leaves and diffuses out through the stomata. This process is called transpiration.
The loss of water creates tension in the xylem. Because water molecules cohere to one another, this tension pulls on the continuous column of water extending down through the plant.
Adhesion between water and the xylem walls helps stabilise the column, while root pressure may make an additional contribution under some conditions.
Capillary effects are therefore part of the story, but they are not the entire explanation.
This is a valuable scientific lesson. Real systems are often controlled by several mechanisms acting together, not by one convenient textbook phrase.
Surface Tension Inside the Lungs
Surface tension is also important inside the lungs.
The alveoli are tiny air sacs where gas exchange occurs. Their inner surfaces are moist, creating an air–water boundary.
Surface tension at this boundary tends to make the alveoli contract. Without a mechanism to reduce it, considerable pressure would be needed to keep the smallest alveoli open.
Specialised cells produce pulmonary surfactant, a mixture that reduces surface tension.
This helps prevent the alveoli from collapsing and reduces the effort required during breathing.
Premature babies may not yet produce enough surfactant, which can lead to serious breathing difficulties. Medical treatment may include providing artificial surfactant and respiratory support.
An idea demonstrated with pepper, detergent and a bowl of water is therefore connected to the mechanics of human breathing.
Why Detergents Clean
Water does not always spread easily across oily or greasy surfaces.
Its relatively high surface tension encourages it to remain in droplets rather than moving into every small gap in a material.
Detergents contain surfactant molecules. One end of a surfactant molecule interacts readily with water, while the other end interacts more strongly with oils and grease.
Surfactants reduce the surface tension of water, allowing it to spread and wet surfaces more effectively. They also help surround oily material in structures called micelles, allowing grease to be carried away in the water.
This is why detergent is useful in washing-up liquid, laundry products and many industrial cleaning systems.
More foam does not necessarily mean more cleaning. Foam may make the product appear active, but the key chemistry involves wetting, emulsification and the interaction between surfactants, water and dirt.
Pens, Printers and Porous Materials
Capillary action is used in many everyday technologies.
In a fountain pen, capillary channels control the movement of ink from the reservoir towards the nib.
In felt-tip pens, the porous material inside the pen stores ink and draws it towards the tip.
Printer cartridges and print heads depend on precisely controlled liquid movement. Engineers must consider viscosity, surface tension, evaporation and the way ink interacts with very small channels.
The same principles influence:
paintbrushes;
sponges;
nappies and absorbent materials;
paper chromatography;
porous building materials;
wicks in candles and oil lamps;
movement of moisture through soil.
A candle wick does not simply burn by itself. Melted wax travels upwards through the wick by capillary action, vaporises near the flame and then burns.
Waterproof Clothing and Surface Design
Waterproof materials are designed to prevent water from spreading into and through the material.
Some surfaces achieve this through chemical coatings with low surface energy. Others combine these coatings with microscopic textures that reduce the area of contact between the droplet and the surface.
Water then forms beads that roll away more easily.
This approach is inspired partly by natural surfaces such as lotus leaves, which possess microscopic structures and waxy coatings.
Engineers can manipulate surface chemistry and texture to produce materials that are:
water-repellent;
stain-resistant;
self-cleaning;
anti-fogging;
easier to sterilise;
better at moving or collecting droplets.
The same scientific principle can be used in opposite ways. A raincoat should resist wetting, while a cleaning cloth should encourage it.
Microfluidics: A Laboratory on a Chip
At very small scales, surface tension and capillary forces become especially important.
Microfluidic devices contain channels that may be narrower than a human hair. Tiny quantities of liquid can be moved, mixed, separated and tested within these channels.
Because the volumes are so small, surface forces may dominate over gravity.
Microfluidic technology is used in:
medical diagnostic tests;
pregnancy tests;
blood analysis;
chemical screening;
environmental monitoring;
DNA analysis;
drug development.
Some devices move liquids using pumps. Others make use of capillary action so that the sample travels through the device without an external power supply.
A familiar lateral-flow test is therefore another example of liquid movement through narrow porous spaces.
Turning the Demonstrations into Better Science
It is easy to perform these activities as entertaining tricks. The greater educational value comes from turning them into investigations.
Students could ask:
How does detergent concentration affect the number of drops a coin can hold?
How does temperature affect surface tension?
How does tube diameter affect capillary rise?
Which material produces the greatest water droplet contact angle?
How does contamination affect a floating needle?
Which type of paper produces the fastest capillary movement?
How does the distance between two glass plates affect the height reached by water?
Students should make predictions before performing each test.
They should also consider:
the independent variable;
the dependent variable;
the control variables;
the precision of the measurements;
the number of repeats;
possible sources of uncertainty;
whether the evidence supports the prediction.
A spectacular demonstration captures attention. A carefully designed investigation develops scientific thinking.
A Personal Reflection: Small Experiments, Large Ideas
Some of the most effective science lessons do not require expensive apparatus.
A bowl of water, a paperclip, a coin, a pipette and a drop of washing-up liquid can introduce intermolecular forces, polarity, biological adaptation, plant transport and medical surfactants.
What matters is the sequence of questions.
Why does the paperclip remain on the surface?
Why does detergent make it sink?
Why does the pepper move?
Why does water rise further in a narrower tube?
Would oil behave in the same way?
Is capillary action enough to lift water to the top of a tree?
When students are encouraged to predict, observe, explain and then challenge their own explanation, a simple demonstration becomes genuine scientific enquiry.
I often find that students remember the dramatic moment when the detergent touches the water. However, the most important stage comes afterwards, when they must replace “the soap pushed it” with a more precise explanation involving molecular attraction and differences in surface tension.
That movement from observation to explanation is at the heart of science.
The Invisible Forces Shaping the Visible World
Water does not really possess a skin, but the description is useful because surface tension produces effects that resemble one.
It supports insects, rounds droplets and can briefly hold a steel paperclip at the surface.
Capillary action allows liquids to move through narrow tubes, paper, soil, plant tissues, pen nibs and medical test devices.
These effects begin with forces acting between molecules. Yet together, those molecular forces influence ecosystems, engineering, cleaning, breathing and the movement of water through living organisms.
The next time a raindrop beads on a leaf, a paper towel absorbs a spill or an insect runs across a pond, we are seeing the same underlying story.
The surface of the water may look quiet and ordinary.
At the molecular level, it is anything but still.

