Making Something Useful from Chemistry: Building a Lead–Acid Accumulator
Chemistry lessons often involve colour changes, precipitates, gases and equations. These can be interesting, but students sometimes leave the laboratory wondering what any of it is actually for.
Making a simple lead–acid accumulator changes that.
Using two carefully prepared lead sheets, dilute sulfuric acid, beakers, connecting wires and a low-voltage power supply, it is possible to construct a device that stores electrical energy chemically. After charging it for only a few minutes, the accumulator can be disconnected from the supply and used to light a small bulb.
For a student, that moment is important.
The bulb may not be especially bright and it may not stay illuminated for very long, but the electricity is no longer coming directly from the power supply. Energy has been stored inside the chemicals and then released again.
That is chemistry doing something useful.
A Battery Built in the Laboratory
The basic apparatus looks surprisingly simple:
two lead sheets;
dilute sulfuric acid;
a beaker;
connecting wires;
a low-voltage direct-current supply;
an ammeter and voltmeter;
a small bulb or suitable low-voltage load.
The lead sheets first need careful preparation. Grease, dirt and surface contamination can prevent good contact between the metal and the electrolyte. In our experiment, the sheets were degreased and soaked in sodium hydroxide solution for approximately 10 minutes before being rinsed and placed in the sulfuric acid.
This preparation is not merely tidying the apparatus. It is part of the science.
Electrochemical reactions happen at the surfaces of the electrodes. A contaminated surface can reduce the effective area available for reaction, increase the internal resistance and make the results much less reliable.
The Royal Society of Chemistry describes a comparable classroom experiment using lead strips and dilute sulfuric acid to demonstrate the operation of a rechargeable lead–acid accumulator.
An Important Correction: An Accumulator Is a Rechargeable Battery
It is easy to describe the investigation as exploring why accumulators are used in cars rather than rechargeable batteries. However, a lead–acid accumulator is a rechargeable battery.
The useful comparison is between a lead–acid accumulator and other rechargeable technologies, such as:
lithium-ion batteries;
nickel-metal hydride batteries;
rechargeable alkaline systems;
newer solid-state or sodium-ion technologies.
The word accumulator emphasises that the device accumulates or stores electrical energy. In modern everyday language, we are more likely to call it a rechargeable battery.
A single lead–acid cell produces a voltage of roughly two volts. A conventional 12-volt car battery contains six such cells connected in series.
Our beaker cell was therefore not intended to reproduce the full performance of a car battery. It was a model that allowed us to investigate the same underlying chemistry.
What Happens During Charging?
Initially, both electrodes are lead. When the cell is connected to a direct-current supply, electrical energy forces chemical changes to take place at their surfaces.
The electrode connected to the positive terminal gradually develops a coating containing lead dioxide, PbO₂. The negative electrode remains largely as lead, although its surface becomes more active and porous.
The charging process is an example of electrolysis. A non-spontaneous chemical change is being driven by an external source of electricity.
This is one of the most useful links students can make between different parts of chemistry. Electrolysis is not simply about producing copper at an electrode or splitting a molten ionic compound. It can also be used to place a chemical system into a higher-energy state.
The electrical supply does not disappear into the cell. Its energy is stored through chemical changes in the electrodes and electrolyte.
What Happens During Discharge?
After charging, the power supply is removed and the cell is connected to a bulb.
The chemical reactions now proceed in the opposite direction. Electrons flow through the external circuit from the negative electrode, through the bulb and towards the positive electrode.
At the negative electrode, lead reacts with sulfate ions:
Pb + SO₄²⁻ → PbSO₄ + 2e⁻
At the positive electrode, lead dioxide reacts with hydrogen ions, sulfate ions and electrons:
PbO₂ + 4H⁺ + SO₄²⁻ + 2e⁻ → PbSO₄ + 2H₂O
The overall discharge reaction is:
Pb + PbO₂ + 2H₂SO₄ → 2PbSO₄ + 2H₂O
Both electrodes gradually become coated with lead sulfate. At the same time, sulfuric acid is consumed and water is formed.
The stored chemical energy is converted back into electrical energy, which is then transferred by the bulb into light and thermal energy.
The Moment the Bulb Lights
There is something particularly satisfying about disconnecting the charging supply, attaching the bulb and seeing it light.
Before that moment, the experiment can appear to be little more than two grey pieces of metal sitting in a colourless liquid. There is no dramatic flame, vivid colour or obvious movement.
Then the bulb glows.
It provides visible evidence that something has changed inside the cell.
This is why practical chemistry matters. A diagram of a lead–acid cell can show the electrodes and equations, but it cannot reproduce the experience of making one work.
The glow of the bulb creates questions:
Where did the energy come from?
Why does the bulb gradually become dimmer?
Why does the terminal voltage fall?
Can the cell be recharged?
How much of the original energy is recovered?
What limits its performance?
These questions turn a demonstration into a genuine scientific investigation.
Measuring the Charging Energy
To calculate the efficiency of the accumulator, we first need to estimate how much electrical energy is supplied during charging.
Electrical energy is calculated using:
Energy = potential difference × current × time
or:
E = VIt
where:
E is energy in joules;
V is potential difference in volts;
I is current in amperes;
t is time in seconds.
Suppose the accumulator is charged at:
3.0 V;
0.40 A;
for 300 seconds.
The charging energy would be:
E = 3.0 × 0.40 × 300
E = 360 J
This assumes that the voltage and current remain approximately constant. For a more accurate investigation, readings should be taken at regular intervals and the energy calculated from the area beneath a power–time graph.
Because:
Power = voltage × current
we can plot power against time. The area beneath that graph represents the electrical energy supplied.
Measuring the Energy Recovered
The charged accumulator is then connected to the bulb or another suitable resistor.
The output energy can again be estimated using:
E = VIt
Suppose the bulb operates with an average potential difference of 1.7 V and an average current of 0.15 A for 240 seconds.
The recovered electrical energy would be:
E = 1.7 × 0.15 × 240
E = 61.2 J
The energy efficiency would then be:
Efficiency = useful energy output ÷ total energy input × 100
Efficiency = 61.2 ÷ 360 × 100
Efficiency = 17%
A simple classroom cell may have quite a low efficiency. That does not mean the experiment has failed. It gives us something more interesting to investigate.
Where Does the Missing Energy Go?
Energy is conserved, but not all of the charging energy can be recovered as useful electrical energy.
Some is transferred through:
heating of the electrolyte;
heating of the wires and electrodes;
electrical resistance inside the cell;
unwanted gas production;
incomplete or competing chemical reactions;
energy remaining chemically stored when the test is stopped;
losses caused by contamination or poor electrode contact.
The bulb itself also converts only part of its electrical input into visible light. Much of the energy becomes thermal energy.
This creates an important distinction.
If we are calculating the electrical efficiency of the accumulator, the useful output is the electrical energy delivered to the bulb.
If we are calculating the efficiency of the complete system as a source of visible light, we would also need to consider the efficiency of the bulb.
That is a much more difficult measurement.
Making the Investigation More Scientific
A single successful demonstration proves that the accumulator can store energy. A proper investigation asks what affects its performance.
Students could investigate:
Charging time
Does doubling the charging time double the energy recovered?
At first, a longer charging period may increase the discharge time. Eventually, however, further charging may produce diminishing returns or encourage unwanted reactions.
Electrode surface area
Larger electrodes provide more surface area for electrochemical reactions. This may reduce internal resistance and allow a larger current to flow.
Distance between the electrodes
Moving the electrodes further apart increases the distance ions must travel through the electrolyte. This can increase resistance and reduce the current.
The electrodes must not touch, as this would short-circuit the cell.
Condition of the lead surfaces
Clean, roughened or porous surfaces may behave differently from smooth or contaminated surfaces.
This makes the lengthy preparation of the lead sheets scientifically significant rather than merely procedural.
Discharge current
A small load may allow the accumulator to operate for longer, while a low-resistance load may draw a larger current but discharge the cell rapidly.
Number of cells
Cells can be connected in series to increase the voltage. They can also be connected in parallel to increase current capacity, although this requires cells with closely matched characteristics.
Voltage Is Not the Same as Stored Energy
Students sometimes measure the terminal voltage and assume that the cell with the highest voltage stores the most energy.
That is not necessarily true.
A cell can produce a measurable voltage but be unable to maintain that voltage when a significant current is drawn. Its internal resistance may be high, or only a small quantity of reactant may be available.
A useful battery must provide both:
an appropriate voltage;
sufficient current for a useful length of time.
This is why measuring only the open-circuit voltage gives an incomplete picture.
The accumulator should also be tested under load. Measuring voltage and current while the bulb is operating reveals much more about its actual performance.
Why Lead–Acid Batteries Are Used in Cars
A petrol or diesel engine needs a substantial burst of electrical power to operate its starter motor. Turning the engine requires a very large current for a relatively short time.
Lead–acid batteries are well suited to this job because they can be designed to provide high power, are relatively inexpensive and have a long-established reputation for reliability. Their disadvantages include low energy per unit mass and a shorter cycle life than some newer chemistries.
This is the central point.
A traditional car battery does not need to provide moderate power for hundreds of kilometres. Its main job is to supply a brief but powerful starting current and then support the vehicle’s electrical systems. Once the engine is running, the alternator recharges it.
Lead–acid batteries are also used for stop–start systems and for ancillary electrical loads in some electric vehicles. The main traction batteries in modern electric vehicles are usually lithium-ion because lithium-ion cells store considerably more energy for their mass and volume.
Why Not Use Lithium-Ion for Every Car Battery?
Lithium-ion batteries are lighter and have much greater energy density. That makes them ideal when weight and stored energy are critical, especially in electric vehicles, phones and laptops.
However, a vehicle’s low-voltage battery has different requirements.
It must be:
dependable;
capable of delivering high current;
tolerant of repeated charging;
economical to replace;
compatible with established vehicle charging systems;
supported by a reliable recycling network.
Lead–acid technology is mature, widely available and comparatively inexpensive. Replacing it is not simply a question of finding a battery that stores more energy. The replacement must satisfy the whole engineering specification.
This is an excellent example of why engineers rarely ask, “Which material is best?”
They ask, “Which material is best for this particular job?”
The Environmental Question
Lead is toxic, and sulfuric acid is corrosive. A lead–acid battery should never be treated as ordinary rubbish.
The technology remains viable partly because collection and recycling systems are already well established. The US Environmental Protection Agency reports a 99% recycling rate for lead–acid batteries in its cited national data and describes a collection network involving retailers, manufacturers and specialist recyclers.
High recycling rates do not make lead harmless. They demonstrate the importance of designing a complete system around a hazardous but useful material.
The environmental judgement therefore cannot be based only on what happens while the battery is inside the car. It must include:
extraction of raw materials;
manufacturing;
working life;
maintenance;
collection;
recycling;
safe handling of lead and acid;
prevention of contamination.
This wider life-cycle thinking is increasingly important across science and engineering.
Safety Must Come First
This is not a casual home experiment.
Sulfuric acid is corrosive, sodium hydroxide is corrosive, lead is toxic, and charging can produce gases if the conditions are not properly controlled. The activity should only be carried out in a suitably equipped laboratory under competent supervision, using an approved risk assessment and appropriate local guidance.
Essential precautions include:
suitable eye protection and protective clothing;
careful control of acid and alkali concentrations;
good ventilation;
avoiding flames and ignition sources;
using a current-limited low-voltage supply;
preventing the electrodes from touching;
washing hands thoroughly after handling lead;
collecting all lead-containing materials and solutions as hazardous waste;
never pouring lead-contaminated liquids down a sink.
The purpose of the experiment is to teach electrochemistry, not to reproduce a commercial battery without industrial safeguards.
From a Beaker to a Car
The laboratory accumulator is small, inefficient and temporary. A car battery is sealed, carefully engineered and constructed with many plates to provide a very large effective surface area.
Yet both depend on the same principles:
oxidation and reduction;
movement of electrons through an external circuit;
movement of ions through an electrolyte;
reversible chemical reactions;
conversion between electrical and chemical energy.
That connection is what makes the investigation so valuable.
Students are not simply memorising half-equations. They are seeing how those equations describe a working energy-storage device.
Chemistry That Earns Its Place
I find experiments like this particularly valuable because they answer a question students often do not ask aloud:
Why are we learning this?
We learn about ions because their movement allows charge to be transported through an electrolyte.
We learn about oxidation states because electrons are transferred during charging and discharging.
We learn about electrolysis because electrical energy can drive chemical change.
We learn about energy calculations because a working device must be measured, compared and improved.
We learn about efficiency because no real system returns all the energy supplied to it in a useful form.
Most importantly, we learn that chemistry is not confined to bottles on a laboratory shelf. It is inside vehicles, phones, emergency power systems, renewable-energy installations and almost every modern electrical device.
Conclusion: When the Chemistry Becomes Real
Two pieces of prepared lead, a beaker of sulfuric acid and some wires do not initially look like an energy-storage system.
After a few minutes of charging, however, they can light a bulb.
That small glow represents a remarkable sequence of energy transfers. Electrical energy has driven chemical reactions, the products have stored energy, and the reverse reactions have released electrical energy into a circuit.
The accumulator may not be especially efficient. Its voltage may fall rapidly and its light may be brief. Those limitations are not reasons to dismiss it. They are opportunities to measure, explain and improve it.
The experiment brings together redox chemistry, electrolysis, electrical circuits, energy, power, efficiency, materials science and environmental responsibility.
Above all, it shows students that chemistry can make something genuinely useful.
Sometimes the best way to understand a battery is not merely to draw one.
It is to build one, charge it and watch the bulb come on.

